Arc casting of intermetallics may sound mundane, however, depending on
the solidification behavior of the constituents inhomgenety, defects,
and other phyical pheonmena may result. Below is an example of solidification
segregation that generates stress in a casting.
Solidification of LaNi5-xSnx
in an plasma/arc furnace
The modified AB5 alloy is used for hydrogen storage.
Upon solidification the Sn is partially rejected and increases
in concentration in
the remaining liquid. Upon completing solidification there is a
great deal of internal stress in the ingot. As the ingot cools
further
the stress is relieved.