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MATERIALS PREPARATION CENTER
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rare earth oxides


Rare earth Metals And Alloys

The Ames Laboratory has been actively involved in the preparation of very pure rare earth metals since the early 1940's when Dr. Frank H. Spedding and his group of pioneers developed the ion-exchange process, a technique that separates the "fraternal fifteen" plus yttrium and scandium. As a result of this and subsequent work, high-purity oxides are available from which high-purity rare earth metals can be prepared. In most cases, the rare earth oxides are first converted to their respective fluorides and are then reduced metallothermically on a kilogram scale, using pure calcium metal specially sublimed for this purpose. The resulting metals are very pure. Nonetheless, many are further refined at the MPC by one of the following processes:

  Purification Techniques
 
  • vacuum casting
  • sublimation
  • distillation
  • zone refining
  • electro-transport processing

Quantities of high-purity rare earth metals and alloys in single and polycrystalline forms are available to scientists outside of Ames Laboratory. Complete chemical analyses, obtained by laser mass spectrometry, inert gas fusion and combustion analysis, accompany the materials. Special preparations of high-purity alloys and compounds are also available in small quantities.

MSDS information for the rare earth elements (metals) are available on-line

 
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